Asymmetric Catalysis Special Feature Part I: Catalytic asymmetric reactions for organic synthesis: The combined C--H activation/Cope rearrangement
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Catalytic asymmetric reactions for organic synthesis: the combined C-H activation/Cope rearrangement.
The development of new catalytic asymmetric reactions can lead to exciting new strategies for organic synthesis. This article describes the synthetic utility of the combined C-H activation/Cope rearrangement, achieved by dirhodium tetraprolinate-catalyzed reaction of vinyldiazoacetates with compounds containing allylic C-H bonds. The transformation is highly diastereoselective and enantioselect...
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ژورنال
عنوان ژورنال: Proceedings of the National Academy of Sciences
سال: 2004
ISSN: 0027-8424,1091-6490
DOI: 10.1073/pnas.0307556101